AC619_966192A_MSDS_EN 20151023
966192A
839736PM
SAFETY DATA SHEET
Print Date: 11-09-2015 Revision Date: 11-09-2015 ______________________________________________________________________________ SECTION 1: IDENTIFICATION OF THE PRODUCT AND SUPPLIER
PRODUCT INFORMATION
PRODUCT: HYSTIC?AC619 2K Structural Acrylic Adhesive(Part A)
PRODUCT DESCRIPTION: Acrylic resin
INTENDED USE: Adhesive
PRODUCT IDENTIFIER: 839736PM
SUPPLIER INFORMATION
Tonsan Suzhou Adhesive Co., Ltd.
40 Youxiang Rd., Wuzhong Economic Development Zone, 215000, Suzhou, China
Telephone: +86-512-87775588
Fax: +86-512-65020968
Tonsan Adhesive, Inc.
5 Shuangyuan Rd. Badachu High-Tech Zone, 100041, Beijing, China
Telephone: +86-10-88795588
Fax: +86-10-68865252
Beijing Hystic New Materials Co., Ltd.
5 Shuangyuan Rd. Badachu High-Tech Zone, 100041, Beijing, China
Telephone: +86-10-68865588
Fax: +86-10-68865252
24 HOUR EMERGENCY PHONE NUMBER: 0532-********
FIRE: 119
SECTION 2: HAZARDS IDENTIFICATION
GHS Hazard
Symbols:
966192A
839736PM
SAFETY DATA SHEET
Print Date: 11-09-2015 Revision Date: 11-09-2015 ______________________________________________________________________________ Safety Precautions: Keep away from heat/sparks/open flames/hot surfaces. – No smoking. Keep container
tightly closed. Ground/bond container and receiving equipment. Use explosion-proof
electrical/ventilating/lighting equipment. Use only non-sparking tools. Take
precautionary measures against static discharge. Do not breathe
dust/fume/gas/mist/vapours/spray. Wash thoroughly after handling. Contaminated work
clothing should not be allowed out of the workplace. Avoid release to the environment.
Wear protective gloves/protective clothing/eye protection/face protection.
First Aid Measures: IF SWALLOWED: rinse mouth. Do NOT induce vomiting. IF ON SKIN: Wash with
plenty of soap and water. IF ON SKIN (or hair): Remove/Take off immediately all
contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove victim to
fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse
cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Call a
POISON CENTER or doctor/physician if you feel unwell. If skin irritation or rash
occurs: Get medical advice/attention. Wash contaminated clothing before reuse. In case
of fire: Use water spray, foam, dry chemical or carbon dioxide to extinguish.
Storage: Keep container tightly closed. Store in a well-ventilated place. Keep cool. Store locked
up.
Disposal: Dispose of contents/container in accordance with local/regional/national/international
regulation for hazardous wastes.
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
This product is a mixture.
Chemical Name CAS # PERCENT Classification Note
Methyl methacrylate 80-62-6 30 - 50 Aquatic Acute 3; H402
Flam. Liq. 2; H225
Skin Irrit. 2; H315
Skin Sens. 1; H317
Methacrylic acid 79-41-4 10 - 30 Acute Tox. 4; H312
Acute Tox. 4; H302
Skin Corr. 1A; H314
Promoter Proprietary 1 - 5 Acute Tox. 4; H302
Eye Irrit. 2; H319
Skin Irrit. 2; H315
Acrylate ester Proprietary 1 - 5 Aquatic Chronic 3; H412
Eye Irrit. 2; H319
Skin Irrit. 2; H315
Acrylate ester Proprietary 1 - 5 Aquatic Chronic 2; H411
Multifunctional acrylate Proprietary 0.1 - 1 Aquatic Chronic 3; H412
Skin Sens. 1; H317
Unlisted components are not classified as hazardous.
SECTION 4: FIRST AID MEASURES
EYE CONTACT: Immediately flush eyes with plenty of water for at least 20 minutes retracting eyelids often. This corrosive material can cause immediate and permanent eye damage. Tilt the head to prevent chemical from transferring to the uncontaminated eye. Get immediate medical attention and monitor the eye daily as advised by your physician.
966192A
839736PM
SAFETY DATA SHEET
Print Date: 11-09-2015 Revision Date: 11-09-2015 ______________________________________________________________________________ SKIN CONTACT: Wash with soap and water. Remove contaminated clothing, launder immediately, and discard contaminated leather goods. Get medical attention immediately.
INHALATION: Remove to fresh air. Restore breathing, if necessary. Call a physician if symptoms persist. INGESTION:Corrosive. Do not induce vomiting! Drink one glass of water followed by milk if available. Seek medical attention immediately. Do not give anything by mouth to an unconscious person. Induced vomiting may lead to aspiration of the material into the lungs potentially causing chemical pneumonitis that may be fatal.
NOTES TO DOCTOR:
SECTION 5: FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: Use water spray, foam, dry chemical or carbon dioxide. UNUSUAL FIRE AND EXPLOSION HAZARDS: Vapors are heavier than air and can travel to a source of ignition
and flash back.
SPECIAL FIRE FIGHTING INSTRUCTIONS: Persons exposed to products of combustion should wear self-
contained breathing apparatus and full protective equipment. HAZARDOUS COMBUSTION PRODUCTS:Carbon dioxide, Carbon monoxide Nitrogen containing gases SECTION 6: ACCIDENTAL RELEASE MEASURES
SPECIAL PROTECTION:Exposure to the spilled material may be severely irritating or toxic.
Follow personal protective equipment recommendations found in
Section 8 of this MSDS. Personal protective equipment needs must be
evaluated based on information provided on this sheet and the special
circumstances created by the spill including; the material spilled, the
quantity of the spill, and the area in which the spill occurred. Never
exceed any occupational exposure limits. Evaporation of volatile
substances can lead to the displacement of air creating an environment
that can cause asphyxiation.
METHODS FOR CLEAN-UP: Dike if necessary, contain spill with inert absorbent and transfer to
containers for disposal. Keep spilled product out of sewers, watersheds,
or water systems.
Shut off ignition sources; including electrical equipment and flames. Do
not allow smoking in the area.
SECTION 7: HANDLING AND STORAGE
HANDLING PRECAUTIONS: Avoid contacting and avoid breathing the material. Use only in a well ventilated area.
Keep away from heat, sparks and flame.
Wash thoroughly after handling.
Keep container closed.
Emptied container retains vapor and product residue.
Observe all labeled precautions until container is cleaned.
Drums of this material should be grounded when pouring.
DO NOT CUT OR WELD ON OR NEAR THIS CONTAINER.
STORAGE ADVICE: Store in a cool, dry, ventilated location. Keep away from heat, sparks, flame and
966192A
839736PM
SAFETY DATA SHEET
Print Date: 11-09-2015 Revision Date: 11-09-2015 ______________________________________________________________________________ other sources of ignition. Keep container closed.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
EXPOSURE LIMITS:
Chemical Name Note CHINESE OCCUPATIONAL
EXPOSURE LIMITS (2007)
ACGIH EXPOSURE LIMITS
Methyl methacrylate 100 mg/m3 TWA
150 mg/m3 STEL 50 ppm TWA 100 ppm STEL
Methacrylic acid 70 mg/m3 TWA
140 mg/m3 STEL
20 ppm TWA
EXPOSURE CONTROL METHODS:
ENGINEERING CONTROLS: Use local exhaust ventilation or other engineering controls to
minimize exposures.
RESPIRATORY PROTECTION: Respiratory protection may be required to avoid overexposure when
handling this product. Use a respirator if general room ventilation is
not available or sufficient to eliminate symptoms. NIOSH approved
air purifying respirator with organic vapor cartridge.
EYE PROTECTION: Wear chemical splash goggles when handling this product.
Additionally, wear a face shield when the possibility of splashing of
liquid exists. Do not wear contact lenses. Have an eye wash station
available.
SKIN PROTECTION: Prevent contact with this product. Wear chemically resistant gloves,
long sleeved shirt, an apron, and other protective equipment
depending on conditions of use. Wear gloves to prevent absorption
through skin.
GLOVES: Butyl rubber
OTHER PROTECTION: No smoking, eating and drinking at work place. Avoid alcoholic
beverages before work. Take a shower and change clothes after work. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Liquid
COLOR: Off-white
ODOR: Characteristic
pH: Not established
FREEZING/MELTING POINT (°C): Not established
BOILING POINT (°C): Not established
FLASH POINT: 12°C; 54°F Pensky-Martens EVAPORATION RATE: Not established
FLAMMABILITY: Not a flammable solid or gas
UPPER EXPLOSION LIMIT: Not established
LOWER EXPLOSION LIMIT: Not established
VAPOR PRESSURE (mm Hg): Not established
966192A
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SAFETY DATA SHEET
Print Date: 11-09-2015 Revision Date: 11-09-2015 ______________________________________________________________________________ VAPOR DENSITY: Not established
RELATIVE DENSITY (WATER=1): 0.940
RELATIVE VAPOR DENSITY (AIR=1): Not established
WATER SOLUBILITY: Not determined
OCTANOL/WATER COEFFICIENT: Not established
IGNITION TEMPERATURE: Not established
DECOMPOSITION TEMPERATURE: Not established
VISCOSITY: No data available.
SOLIDS (% by weight): 100.0
VOC, weight percent Not determined
MAJOR FUNCTION: Adhesive
SECTION 10: STABILITY AND REACTIVITY
STABILITY: May become unstable at elevated temperatures. CONDITIONS TO AVOID: Temperatures greater than 90 F (32 C). Temperatures
greater than 40 F (4 C). Sunlight.
CHEMICAL INCOMPATIBILITY: Free radical initiators
HAZARDOUS POLYMERIZATION: May occur. Self heating material.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide Nitrogen
containing gases
SECTION 11: TOXICOLOGICAL INFORMATION
Component Toxicity / Toxicology Data:
COMPONENT NAME LD50/LC50
Methyl methacrylate INHALATION LC50-4H RAT 4,632.00 PPM
Methacrylic acid INHALATION LC50-4H RAT 7.10 MG/L
POTENTIAL HEALTH EFFECTS BY ROUTE OF ENTRY:
Skin corrosion / irritation:Contact causes severe skin irritation and possible burns.
Serious eye damage / irritation: Corrosive to eye tissue. Can cause severe irritation, tearing, and burns that can
quickly lead to permanent injury including blindness.
Respiratory / skin sensitization: May cause an allergic skin reaction.
Germ cell mutagenicity: No data available.
Carcinogenicity: No data available.
Reproductive toxicity: No data available.
Single Exposure Target Organ Effects: No data available.
Respiratory irritation / Narcotic effects: May cause respiratory irritation.
Repeated Exposure Target Organ Effects: No data available.
Target Organs Potentially Affected by
Skin
Exposure:
Aspiration hazard: Not an aspiration hazard.
Medical Conditions Aggravated by Exposure: Skin disease including eczema and sensitization
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SAFETY DATA SHEET
Print Date: 11-09-2015 Revision Date: 11-09-2015 ______________________________________________________________________________ SECTION 12: ECOLOGICAL INFORMATION
OVERVIEW: No ecological information available for this product.
MOBILITY: No data available.
PERSISTENCE: No data available.
BIOACCUMULATION: No data available.
This product has not been tested for ecological effects. Relevant information for components is listed below: Component Ecotoxicity values:
Methyl methacrylate Acute Toxicity (Fish): 96 Hr LC50 Pimephales promelas: 243 - 275 mg/L [flow-
through]; 96 Hr LC50 Pimephales promelas: 125.5 - 190.7 mg/L [static]; 96 Hr LC50
Lepomis macrochirus: 170 - 206 mg/L [flow-through]; 96 Hr LC50 Lepomis
macrochirus: 153.9 - 341.8 mg/L [static]; 96 Hr LC50 Oncorhynchus mykiss: >79 mg/L
[flow-through]; 96 Hr LC50 Oncorhynchus mykiss: >79 mg/L [static]; 96 Hr LC50
Poecilia reticulata: 326.4 - 426.9 mg/L [static]
Acute Toxicity (Daphnia): 48 Hr EC50 Daphnia magna: 69 mg/L
Acute Toxicity (Algae): 96 Hr EC50 Pseudokirchneriella subcapitata: 170 mg/L
SECTION 13: DISPOSAL CONSIDERATIONS
DISPOSAL METHODS: Disposal should be in accordance with local or national legislation.
SECTION 14: TRANSPORT INFORMATION
Consult Bill of Lading for transportation information.
IATA: UN1866, RESIN SOLUTION, 3, II
AUSTRALIA ADG: UN1866, RESIN SOLUTION, 3, II
Not applicable
TRANSPORTATION
INSTRUCTION
SECTION 15: REGULATORY INFORMATION
INVENTORY STATUS
CHINA IECSC INVENTORY: This product is in compliance with the Inventory of Existing Chemical
Substances in China (IECSC) requirements.
U.S. EPA TSCA: This product is in compliance with the Toxic Substances Control Act's
Inventory requirements.
CANADIAN CEPA DSL: This product contains one or more components which have not been
determined to be on the DSL. If you are the importer of this product
into Canada, contact H.B. Fuller for chemical tracking and notification
information.
EUROPEAN REACH: As supplied, this product does not meet the registration requirements
under REACH. Articles using this product may be imported into the
European Union. See below for information on SVHC content.
AUSTRALIA AICS: This product contains a component that is not on the Australian
Inventory (AICS).
966192A
839736PM
SAFETY DATA SHEET
Print Date: 11-09-2015 Revision Date: 11-09-2015 ______________________________________________________________________________ Substances of Very High Concern (SVHC) Content:
Unless listed below, this product does not contain SVHC’s.
SECTION 16: OTHER INFORMATION
SDS VERSION DATE: 11-09-2015
This Safety Data Sheet meets Chinese standards and regulations, but may not meet the requirements of other countries.
This Safety Data Sheet has been prepared in accordance with GBT16483-2008.
Prepared by: The Global Regulatory Department
Phone: 651-236-5842
The information and recommendations set forth herein are believed to be accurate. Because some of the information is derived from information provided to the H.B. Fuller Company from its suppliers, and because the H.B. Fuller Company has no control over the conditions of handling and use, the H.B. Fuller Company makes no warranty, expressed or implied, regarding the accuracy of the data or the results to be obtained from the use thereof. The information is supplied solely for your information and consideration, and the H.B. Fuller Company assumes no responsibility for use or reliance thereon. It is the responsibility of the user of H.B. Fuller Company products to comply with all applicable federal, state and local laws and regulations.