2016年复大化学系物理化学考研真题凯程独家分析.

2016年复大化学系物理化学考研真题凯

程独家分析

刚考完2016考研初试，凯程教育的电话瞬间变成了热线，同学们兴奋地汇报自己的答题情况，几乎所有内容都在凯程考研集训营系统训练过，所考专业课难度与往年相当，答题的时候非常顺手，相信凯程的学员们对此非常熟悉，预祝亲爱的同学们复试顺利。考研分笔试、面试，如果没有准备，或者准备不充分，很容易被挂掉。如果需要复试的帮助，同学们可以联系凯程老师辅导。

下面凯程老师把专业的真题全面展示给大家，供大家估分使用，以及2017年考研的同学使用，本试题凯程首发!

一、简答题

1. 具体阐述洪特规则

2. 简述slater行列式的意义

3. 统计热力学的基本假设是什么

4. 化学势的定义？其引出解决了热力学的哪些问题？

5. 当反应体系中不止一个产物时，怎样利用热力学和动力学因素加以选择和判断？

二、计算和讨论题

1. （1）CO和H2O都可以与金属原子形成配位键，但是前者与金属间的键更强，为什么？（2）CO可以与两金属原子形成桥连键，也可以与金属原子形成端位键，哪一种键的振动频率更大？为什么？

2. 具体列出了金刚石两原子间的距离和密度，（1）假设金刚石是密堆积，且为立方面心，计算出其密度，解释为何和实际密度不一样？（2）现已知道金刚石一个晶胞中含有8个C原子，则(111)晶面间距是多少？

3. 学习指导15-5原题

4. 学习指导11-22原题

5. 学习指导12-62原题

6. 复旦期末卷子的一道证明题：

合成氨的反应机理：

N2+2(Fe)→2N(Fe) （1）速控（k1）

N(Fe)+3/2H2→NH3+(Fe) （2）对峙（正向k2，逆向k-2）

假定(Fe)和N(Fe)的浓度之和为常数，试证明：

file:///C:/Users/lenovo/AppData/Local/Temp/msohtmlclip1/01/clip_image002.png（word下的公式没法黏贴到这里，想要word文档的可以加我）

（式中K=k-2/k2,k为常数）

7. 给出了乙烯水合反应的标准吉布斯反应自由能变与温度的关系式，（1）求标准反应焓变与温度的关系式（2）求再T=573K时的平衡常数（3）求T=573K时的标准反应熵变

Ps.这道题可以参考学习指导14-39，知识点是类似的

8. 氯化铵在300K下部分分解达到平衡时总压为104.6KPa，而碘化铵在相同条件下达到平衡时的总压为18.8KPa，则当有足量氯化铵与碘化铵在同一容器中达到平衡时，总压为多少？假设两者不形成固溶体，气体视为理想气体。

9. 平行反应，反应开始时A与B的浓度均为0.5mol.dm-3

A+B→C（主反应，活化能E1，速率常数k1）

A+B→D（副反应，活化能E2，速率常数k2）

（1）500K下，当反应进行30min时，C和D的浓度分别为0.075和0.125mol.dm-3，分别计算k1与k2（2）已知E1为150KJ.mol-1，假设两个平行反应的指前因子相同，求E2（3）列出相应公式说明怎样能提高反应的选择性

10. 电池，H2（P标准）/HI(m)/AuI+Au

（1）写出电池反应（2）计算某浓度下的活度系数（3）计算AuI的Ksp（具体数据不太记得了）

2016年考研英语一真题及答案

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2016考研英语二真题：小作文解析

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2016年考研管理类联考英语二真题.pdf

2016年考研管理类联考英语二真题

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