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韶关市2014届高三调研测试化学试题

韶关市2014届高三调研测试

理综化学试题

可能用到的相对原子质量:H 1 C 12 N 14 O 16 Na 23 Mg 24 S 32 Cl 35.5 K 39 Mn 55

Fe 56

7.下列说法正确的是

A.苯、油脂均不能使酸性KMnO4溶液褪色

B.乙烯和1,3-丁二烯互为同系物,它们均能使Br2水褪色

C.葡萄糖、果糖的分子式均为C6H12O6,二者互为同分异构休

D.乙醇、乙酸均能与Na反应放出H2,二者分子中官能团相同

8.设N A为阿伏加德罗常数的数值,下列叙述正确的是

A.1 L 1 mol/L氯化铜溶液中含有N A个Cu2+

B.标准状况下,22.4 L O2参加任何化学反应转移的电子数都是4N A

C.1 mol Zn与足量稀HNO3反应,转移2N A个电子

D.1 mol H3O+所含电子数为8N A

9.下列有关离子组的评价及相关离子方程式均正确的是:

离子组评价及离子方程式

A

H+、Fe2+、NO3-、

Cl-

不能大量共存于同一溶液中,因为发生反应:

Fe2+ + 2H+ = Fe3+ + H2↑

B

Na+、K+、HCO3-、

OH-

不能大量共存于同一溶液中,因为发生反应:

HCO3- + OH- = H2O+ CO2↑

C

Ca2+、NH4+、

CO32-、Cl-

能大量共存于同一溶液中

D

Na+、NH4+、

SO42-、Cl-

能大量共存于同一溶液中

10.下列叙述正确的是

A.向明矾溶液中加入过量NaOH溶液会产生大量白色沉淀

B.Na2O2用作呼吸面具的供氧剂

C.氯水中通入SO2后溶液的酸性减弱

D.N2与O2在放电条件下直接化合生成NO2

11.四种短周期元素在周期表中的位置如右图,其中只有M元素原子最外层电子数与电子层数相等,下列说法不正确

...的是

A.原子半径Z

B.Y的最高价氧化物对应水化物的酸性比X的弱

C.非金属性:X

D .M 元素最高价氧化物对应水化物具有两性

12.对处于平衡状态的反应2A (g )+B(g)2C(g) △H <0,下列叙述正确的是

A .增大A 浓度的瞬间,正V 增大,V 逆不变

B .升高温度,正V 减小,V 逆增大

C .增大压强.正V 增大,V 逆减小

D .加入催化剂,正V 、V 逆都增大

22.常温下,浓度均为0.1mol/L 的三种溶液:①CH 3COOH 溶液②NaOH 溶液③CH 3COONa 溶液,下列说法中正确的是(忽略混合前后溶液体积变化)

A .溶液的pH 值:②>③>①

B .水电离出的c(OH -

):③>①=②

C .①和③等体积混合后的溶液:c(CH 3COOH)+ c(CH 3COO -

)=0.1mol/L D .②和③等体积混合后的溶液:c(Na +)=c(CH 3COOH)+c(CH 3COO -

)

30.(16分)工业上用甲苯生产对羟基苯甲酸乙酯

COOC 2H 5

O

H ,生产过程如下图:

(1)对羟基苯甲酸乙酯的分子式为____ ____;1mol 该物质与NaOH 溶液完全反应,最多消耗___ ___molNaOH 。

(2)化合物A 中的官能团名称是_________,反应④的反应类型属_____ ___。 (3)反应①的化学方程式________ _______。

(4)在合成线路中,设计第③和⑥这两步反应的目的是__________。

(5)有机物C (分子构型为 ,-X 、-Y 为取代基)是对羟基苯甲酸乙酯的同分异构体且

能发生银镜反应,则-X 的结构简式可能是 、 。

31.(15分)

(1)已知: C(s)+O 2(g)=CO 2(g) ΔH 1=-393.5 kJ/mol

C(s)+H 2O(g)=CO(g)+H 2(g) ΔH 2=+131.3 kJ/mol

则反应CO(g)+H 2(g) +O 2(g)= H 2O(g)+CO 2(g),ΔH = ____ ___kJ/mol 。 (2)在一恒容的密闭容器中,由CO 和H 2合成甲醇:CO(g)+2H 2(g)CH 3OH(g) ΔH

①下列情形不能..说明该反应已达到平衡状态的是_______(填序号)。 A .每消耗1 mol CO 的同时生成2molH 2 B .混合气体总物质的量不变

C .生成CH 3OH 的速率与消耗CO 的速率相等

D .CH 3OH 、CO 、H 2的浓度都不再发生变化

Y

X

X 3

CH 3

OH

OCH 3

CH 3

OCH 3

COOH

COOC 2H 5

OH

CH 3I

HI

C 2H 5OH

酸性KMnO 4

②CO的平衡转化率(α)与温度、压强的关系如右图所示。A、B两点的平衡常数K(A)_______K(B)(填“>”、“=”或“<”,下同);由图判断ΔH __ ___0。

③某温度下,将2.0 mol CO和6.0 molH2充入2 L的密闭容器中,充分反应后,达到平衡时测得

c(CO)=0.25 mol/L,则CO的转化率=__ ___,此温度下的平衡常数K=___ __(保留二位有效数字)。

(3)工作温度650℃的熔融盐燃料电池,用煤炭气(CO、H2)作负极反应物,空气与CO2的混合气体为正极反应物,催化剂镍作电极,用一定比例的Li2CO3和Na2CO3低熔点混合物作电解质。负极的电极反应式为:CO+H2-4e-+2CO32-=3CO2+H2O;则该电池的正极反应式为__ _____。

32.(16分)工业上生产高氯酸(沸点:90°C)时还同时生产了亚氯酸钠,其工艺流程如下:

1)实验室进行过滤操作的常用玻璃仪器有。

(2)反应器I中的温度最佳为(填序号);操作②的名称为。

A. 0°C ;

B. 20°C ;

C. 80°C ;

D. 120°C

(3)反应器II中发生反应的离子方程式为。

(4)加快反应器II中反应速率的措施有(写出一种措施即可)等。从反应器II中获得NaClO2粗品的实验操作依次是(填序号,下同),进一步提纯的操作名称为。

A.过滤

B. 重结晶

C.蒸馏

D.蒸发浓缩

E. 蒸干灼烧

F. 冷却结晶

G.萃取分液

(5)上述流程中可循环使用的物质为,副产品除NaClO2、NaHSO4外还有

(填化学式)。

33.(17分)绿矾(FeSO4?7H2O)是中学阶段常用的一种还原剂。

(1)久置的绿矾溶液容易被空气氧化变质,简述检验绿矾溶液已经变质的操作和现象:取少量待测液于试管中,。

(2)绿矾溶液浓度的标定

测定溶液中Fe2+物质的量浓度的方法是:a.量取25.00mL待测溶液于锥形瓶中;b.用硫酸酸化的0.01000mol/L KMnO4溶液滴定至终点;c.重复操作2次,消耗KMnO4溶液体积的体积分别为20.02mL、24.98mL、19.98mL。

(已知滴定时发生反应的离子方程式为5Fe2++MnO4—+8H+=5Fe3++Mn2++4H2O)

①判断此滴定实验达到终点的方法是。

2+

【反应原理】Fe2+在空气中易氧化变质,完成并配平下列离子方程式:

Fe2+ + O2 + = Fe(OH)3↓+ Fe3+

【操作与现象】取4支试管,如图进行实验,请在相应位置上写出试管①、③的现象。

【分析与结论】设计试管①的作用是;为了有效保存FeSO4溶液,你认为最佳方案为。

化学答案及评分参考

7.C 8.C 9.D 10.B 11.B 12.A 22.A C 23.B D 30.(16分)

(1)C 9H 10O 3 (2分); 2(2分) (2)氯原子(2分); 氧化反应 (2分) (3) (2分)

(4)防止酚羟基被氧化(或答“保护酚羟基”、第③步将-OH 转化为-OCH 3,第⑥步将-OCH 3,转化为-OH 等均对)(2分)

(5)-OH 、-CH 2OH (或-OCH 3、各2分) 31.(15分)

(1)-524.8(2分)

(2)①c (2分);② =(2分);<(2分);③75%(3分); 1.3(2分) (3)O 2+4e -+2CO 2=2CO 32-(2分) 32.(16分)

(1)(普通)漏斗、玻璃棒、烧杯(3分,各1分) (2)C ; 蒸馏 (各1分)

(3)2ClO 2+SO 2+4OH -=2ClO 2-+SO 42-+2H 2O (2分)

(4)适当升高温度(增大NaOH 溶液的浓度、增大气体(SO 2、ClO 2)和NaOH 溶液的接触面积等)

(2分);DF(A)(2分);B (1分) (5)硫酸;Na 2SO 4 (各2分)

33.(17分)

(1)向其中滴入2~3...滴的..KSCN ....溶液,震荡,溶液变成红色......。 (2分) (2)①当最后一滴....KMnO 4溶液滴入锥形瓶后,瓶内溶液变成浅红色...且半分钟内不褪色.......

。 (2分)

②0.04000 mol/L (3分,计算结果1分,有效数字1分,单位1分) (3)【反应原理】 12、3、6 H 2O ;4、8 (3分,物质1分,配平2分) 【操作与现象】少量(3滴)硫酸(2分);

溶液颜色很快..变.成黄色...,并出.现.棕黄色...浑浊..(2分) 【分析与结论】作空白对照实验(1分);

用煤油隔绝空气,并加入少量的铁屑和稀硫酸(2分)

+ Cl 2 + HCl

3

3

Cl

催化剂

30.

(1);

(2);

(3)

(4)

(5);

31.

(1)

(2)①②;

③;

(3)

32.

(1)

(2);

(3)

(4)_;

(5);

33.

(1)

(2)①

(3)【反应原理】Fe2++O2 + = Fe(OH)3↓+ Fe3+

【操作与现象】试剂

现象

【分析与结论】;

2019届高三上学期英语期末考试试卷第3套真题

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