GNE-7915_LCMS_14628_MedChemExpress

File ..ata\20170920\20170920-1\CPK2017-920-14628.D Tgt Mass (CHM): Injection Date : 20 Sep 17 6:33 pm +0800 Seq. Line : 51 Sample Name : CPK2017-920-14628 Location : P1-F-10 Acq. Operator : SYSTEM Inj : 1 Spec. Reported : MS Integration Inj Volume : 1 ul Acq. Method : D:\LCMS03\Data\20170920\20170920-1\1-POS-3MIN.M Analysis Method : D:\LCMS03\Data\20170920\20170920-1\1-POS-3MIN.M Catalog No : HY-18163 Batch#14628

Method Info : Mobile Phase: A: water(0.01%TFA) B:ACN(0.01%TFA) Gradient: 5% to 95%B within 1.3 min Flow Rate :1.8ml/min

Column :SunFire C18, 4.6*50mm,3.5um A-RP-186 Oven Temperature : 45C

min

00.51

1.5

2 2.5mAU 0

200400600 DAD1 A, Sig=214,4 Ref=off

1.173

1.3661.424

1.683

1.725

min

00.51 1.5

2

2.5

mV 0

50100150 ELS1 A, ELSD Signal 1.747

min 00.51

1.52

2.5

2000000

4000000

6000000 MSD1 TIC, MS File ES-API, Pos, Scan, Frag: 70

0.224

0.339

0.563

1.209

1.405

1.478

1.715

1.829

2.013

2.283

2.367

2.489

2.582

2.672

2.814

2.911

min

0.5

1

1.52

2.5

02500

5000750010000 Ion 443.4, MSD1 443.4,Target Mass 443.4 Positive, EIC=443.1:444.1

2.254

Integration Results for DAD1 A, Sig=214,4 Ref=off

RetTim Width Area Height Area% MS(+)|-------|--------|--------------|--------------|--------|------| 1.17 0.01 3.20 3.68 0.41 325 1.37 0.01 1.38 1.81 0.18 233 1.42 0.01 2.56 3.00 0.33 233 1.68 0.02 761.25 757.35 98.14 444 1.72 0.01 7.28 9.31 0.94 444

Integration Results for MSD1 TIC, MS File

RetTim Width Area Height Area% MS(+)|-------|--------|--------------|--------------|--------|------| 0.22 0.06 38289.19 11451.33 0.12 253 0.34 0.10 170417.59 27189.95 0.52 102 0.56 0.06 51064.23 14533.15 0.16 253 1.21 0.06 416643.22 100863.47 1.27 325 1.41 0.06 67435.37 17302.87 0.21 233 1.48 0.07 115627.30 32627.63 0.35 233 1.71 0.06 28020206.00 7578811.00 85.30 444 1.83 0.04 305643.84 123675.13 0.93 179 2.01 0.06 403354.38 113203.98 1.23 105

2.28 0.21 2735896.25 183714.50 8.33 105 2.37 0.07 98426.71 22511.48 0.30 105 2.49 0.04 43255.97 16871.47 0.13 105 2.58 0.05 130052.50 40907.89 0.40 105 2.67 0.05 71768.10 24046.51 0.22 105 2.81 0.04 7150

3.93 27738.21 0.22 105 2.91 0.05 110289.57 45240.84 0.34 105

Ret. Time: 0.22 <<<< POSITIVE SPECTRA >>>>

m/z

100200

300400500

600

700

800

900

01000

2000

3000

4000

5000

ES-API Positive

209.9

305.9

104.1269.0

138.2245.3

360.3

401.2

168.1

188.8

254.1

141.1

169.1328.1

193.9

275.0

312.1

102.2

179.1338.4

235.0170.1

120.1253.1

Ret. Time: 0.34

m/z 100200

300

40050060070080090001000

2000

3000

4000

ES-API Positive 236.1

145.0

360.1

100.9305.4401.2

216.9185.2

121.0

284.2

323.0260.2

157.1194.0

312.0

255.1136.1

338.3

275.0

235.0

179.1120.1169.1170.1

253.1

102.2Ret. Time: 0.56

m/z

100

200

300

400

500600700800

900

05001000

1500

2000

2500

3000

3500

4000

ES-API Positive 174.3

796.8

366.0

296.1214.1

257.2

153.1

236.0

132.2

195.2315.4418.4

394.3

112.2

334.3276.0312.3

338.3

275.1

171.1

239.0

141.1

169.1

102.2

170.1

120.1

253.0

MS Report from Instrument: LCMS-03

Ret. Time: 1.21

m/z

100200300400500600700

800

900

02500

5000

7500

10000

12500

15000

17500

20000

ES-API Positive

171.1

328.3

273.1

130.1217.2393.3235.1233.1170.1370.3

253.1102.2

305.1148.1

349.2327.1325.2Ret. Time: 1.41

m/z 100200300400

500600

70080090002000

4000

6000

8000

10000

ES-API Positive 173.1230.2278.0208.9

126.1

396.1259.2650.5

101.1472.3

532.2451.3

494.3

155.1565.5

327.2

365.2300.1277.1

542.3

312.0395.2179.1

252.9217.1

102.2471.4

493.4141.1255.1

325.2564.4

105.1

314.1233.1Ret. Time: 1.48

m/z

100

200

300

400

500

600

700

800

900

02000

4000

6000

8000

10000

12000

14000

ES-API Positive

325.2388.3

297.0

494.3258.2277.1239.0149.0

209.1171.1541.5

649.4

584.3

191.1465.1

437.1

564.3

764.4130.0740.4

606.4344.3

370.6493.4

312.1

179.2102.2

217.1

141.2

261.1

605.4

763.6

305.1

105.1

762.5

233.1

MS Report from Instrument: LCMS-03

m/z

100

200

300

400

500

600

700

800

900

0200000

4000006000008000001E61.2E61.4E6910.3

445.2

909.3

444.2

Ret. Time: 1.83

m/z

100

200

300

400

500

600

700

800

900

010000

20000

30000

40000

50000

ES-API Positive

141.1275.1

345.1

159.0

247.1

584.2

217.1

466.1

430.1393.3

102.2

910.3312.3

606.2

180.1

370.4

261.1

441.2338.3

233.1

105.1

305.2

444.2179.1

Ret. Time: 2.01

m/z

100

200

300

400

500

600

700

800

900

05000

1000015000

2000025000

300003500040000 ES-API Positive

169.1

431.0

130.1

613.3

769.2

199.9

234.1

403.1

633.2

102.2

360.3

339.3

306.1

444.2

265.2612.2261.1

305.1

179.1

233.1

338.3

611.3

105.1

m/z

100

200

300

400

500

600

700

800

900

050000

100000

150000

200000

106.1

179.2

141.1349.2

199.9

261.1

159.0

233.1

431.0

305.2

338.3

Ret. Time: 2.37

m/z

100

200

300

400

500

600

700

800

900

050000

100000

150000

200000250000300000350000 ES-API Positive

106.1

349.2141.1200.0

233.2

261.1

159.0

431.0305.2

338.4

360.3

105.1

Ret. Time: 2.49

m/z

100

200

300

400

500

600

700

800

900

050000

100000

150000

200000250000300000350000 ES-API Positive

106.1141.2349.1

200.0

233.1

261.1

159.0

430.9305.2

338.4

360.3

105.1

m/z

100

200

300

400

500

600

700

800

900

050000

100000

150000200000250000300000141.1106.1349.2

200.0

233.1

261.1

408.3

159.0

430.9

305.2

338.3

Ret. Time: 2.67

m/z

100

200

300

400

500

600

700

800

900

050000

100000

150000

200000250000300000350000 ES-API Positive

349.2

106.1

141.2200.0

233.1

261.1

159.0

430.9305.1

338.3360.3

105.1

Ret. Time: 2.81

m/z

100

200

300

400

500

600

700

800

900

050000

100000

150000200000250000300000350000 ES-API Positive

361.3294.0

106.1

141.1339.3

200.0

233.1

261.1

159.0

430.9360.4

338.3

105.1

m/z

100

200

300

400

500

600

700

800

900

050000

100000

150000200000250000300000350000106.1

141.1294.0

200.0

233.1

261.1

159.0

349.2

430.9

338.4

360.4

105.1

*** End of Report ***