生成焓表

Miscellaneous Compounds

Species Phase(Matter) Chemical Formula ΔH

f

o (kJ/mol) Aluminum

Solid Al 0

Solid AlCl

3

-705.63

Solid Al

2O

3

-1675.7

Solid BaCl

2

-858.6

Solid BaCO

3

-1213 Solid BaO -548.1

Solid BaSO

4

-1473.2 Solid Be 0

Solid Be(OH)

2

-902.5

Solid BCl

3

-402.96

Liquid Br

2

Gas Br 111.884

Gas Br

2

30.91

Gas BrF

3

-255.60 Gas HBr -36.29 Solid Ca 0

Gas Ca 178.2

Gas Ca2+1925.90 Solid CaC

2

-59.8

Solid CaCO

3

-1207.6

Solid CaCl

2

-795.8

Solid Ca

3(PO

4

)

2

-4132

Solid CaF

2

-1219.6

Solid CaH

2

-186.2

Solid Ca(OH)

2

-986.09

Aqueous Ca(OH)

2

-1002.82 Solid CaO -635.09

Solid CaSO

4

-1434.52 Solid CaS -482.4

Alkanes Above

Liquid C

6H

6

48.95

Solid C

7H

6

O

2

-385.2

Solid C 0

Solid C 1.8

Gas C 716.67 Gas CO

2

-393.509

Liquid CS

2

89.41

Gas CS

2

116.7 Gas CO -110.525

Liquid CCl

4

-139.5

Gas CCl

4

-103.18

Gas COCl

2

-218.8

Gas C

2H

6

-83.85

Liquid C

2H

5

OH -277.0

Gas C

2H

5

OH -235.3

Gas C

2H

4

52.47

Gas C

2H

2

226.73

Gas CH

4

-74.87

Liquid CH

3

OH -238.4

Gas CH

3

OH -201.0

Liquid CHCl

3

-134.47

Gas CHCl

3

-103.18

Liquid C

3H

8

-104.7

Solid Cs 0

Gas Cs+457.964 Solid CsCl -443.04 Gas Cl

2

Solid Cr 0

Solid Cu 0

Gas F

2

Gas H

2

Liquid H

2

O -285.83

Gas H

2

O -241.83

Liquid H

2O

2

-187.78

Gas HCN +130.5 Gas HI +26.5 Gas HF -269 Gas HCl -92.30 Solid I

2

Gas I

2

62.438

Solid MgCO

3

-1111.69

Solid MgCl

2

-641.8

Solid Mg(OH)

2

-924.54

Solid MgO -601.24

Solid MgSO

4

-1278.2 Solid MnO -384.9

Solid MnO

2

-519.7 Solid HgO -90.83 Solid HgS -58.2

Aqueous NH

3

-80.8

Gas NH

3

-45.90

Gas NO

2

33.1 Gas NO 90.29 Gas O 249

Gas O

3

143

Liquid PCl

3

-320

Solid PCl

5

-440

Solid KBr -392.2

Solid KClO

3

-397.73 Solid KCl -436.68 Solid KF -562.6

Solid KClO

4

-430.12

Solid SiO

2

-910.86 Solid AgBr -99.5 Solid AgCl -127.01 Solid AgI -62.4

Solid Ag

2

O -31.1

Solid Ag

2

S -31.8

Solid Na

2CO

3

-1130.77

Aqueous NaCl -407.27

Solid NaCl -411.12 Liquid NaCl -385.92 Gas NaCl -181.42 Solid NaF -569.0 Aqueous NaOH -469.15 Solid NaOH -425.93 Aqueous NaNO

3

-446.2

Solid NaNO

3

-424.8

Gas H

2

S -20.63

Gas SO

2

-296.84

Liquid H

2SO

4

-814

化学标准生成焓表

Species Phase(Matter) Chemical Formula ΔH f o (kJ/mol) Solid Al 0 Solid AlCl 3 -705.63 Solid Al 2O 3 -1675.7 Solid BaCl 2 -858.6 Solid BaCO 3 -1213 Solid BaO -548.1 Solid BaSO 4 -1473.2 Solid Be 0 Solid Be(OH) 2 -902.5 Solid BCl 3 -402.96 Liquid Br 2 Gas Br 111.884 Gas Br 2 30.91 Gas BrF 3 -255.60 Gas HBr -36.29 Solid Ca 0 Gas Ca 178.2 Gas Ca2+1925.90 Solid CaC 2 -59.8 Solid CaCO 3 -1207.6 Solid CaCl 2 -795.8 Solid Ca 3(PO 4 ) 2 -4132 Solid CaF 2 -1219.6 Solid CaH 2 -186.2 Solid Ca(OH) 2 -986.09 Aqueous Ca(OH) 2 -1002.82 Solid CaO -635.09 Solid CaSO 4 -1434.52 Solid CaS -482.4 Alkanes Above Liquid C 6H 6 48.95

Solid C 7H 6 O 2 -385.2 Solid C 0 Solid C 1.8 Gas C 716.67 Gas CO 2 -393.509 Liquid CS 2 89.41 Gas CS 2 116.7 Gas CO -110.525 Liquid CCl 4 -139.5 Gas CCl 4 -103.18 Gas COCl 2 -218.8 Gas C 2H 6 -83.85 Liquid C 2H 5 OH -277.0 Gas C 2H 5 OH -235.3 Gas C 2H 4 52.47 Gas C 2H 2 226.73 Gas CH 4 -74.87 Liquid CH 3 OH -238.4 Gas CH 3 OH -201.0 Liquid CHCl 3 -134.47 Gas CHCl 3 -103.18 Liquid C 3H 8 -104.7 Solid Cs 0 Gas Cs+457.964 Solid CsCl -443.04 Gas Cl 2 Solid Cr 0 Solid Cu 0 Gas F 2 Gas H 2 Liquid H 2 O -285.83 Gas H 2 O -241.83 Liquid H 2O 2 -187.78 Gas HCN +130.5 Gas HI +26.5 Gas HF -269

一些物质的标准生成焓、标准吉布斯函数和 25℃、100kPa 时的绝对熵

附表18 一些物质的标准生成焓、标准吉布斯函数和25℃、100kPa 时的绝对熵 附表18 一些物质的标准生成焓、标准吉布斯函数和25℃、100kPa 时的绝对熵 0f H Δ 0f G Δ 0m S 物质 分子式 相对分子质量 M r J/mol J/mol J/(mol K)? 水(g) 水(l) 过氧化氢(g) 臭氧(g) 碳(石墨)(s) 一氧化碳(g) 二氧化碳(g) 甲烷(g) 乙炔(g) 乙烯(g) 乙烷(g) 丙烯(g) 丙烷(g) 丁烷(g) 戊烷(g) 苯(g) 己烷(g) 庚烷(g) 辛烷(g) 辛烷(l) 甲醇(g) 乙醇(g) 氨(g) 柴油(l) 硫(s) 二氧化硫(g) 三氧化硫(g) 氧化氮(g) 硝基甲烷(l) H 2O H 2O H 2O 2O 3C CO CO 2CH 4C 2H 2 C 2H 4C 2H 6C 3H 6 C 3H 8C 4H 10C 5H 12 C 6H 6C 6H 14C 7H 16 C 8H 18C 8H 18CH 3OH C 2H 5OH NH 3C 14.4H 24.9 S SO 2SO 3N 2O CH 3NO 2 18.015 18.015 34.015 47.998 12.011 28.011 44.010 16.043 26.038 28.054 30.070 42.081 44.094 58.124 72.151 78.114 86.178 100.20511 4.232 114.232 32.042 46.069 17.031 198.06 32.06 64.059 80.058 44.013 61.04 -241826-285830-136106+142674 0 -110527 -393522-74873 +226731 +52467 -84740 +20430 -103900-126200 -146500 +82980 -167300-187900 -208600-250105-201300 -235000-45720 -174000 0 -296842-395765+82050 -113100 -228582 -237141 -105445 +163184 0 -137163 -394389 -50768 +209200 +68421 -32885 +62825 -23393 -15970 -8208 +129765 +28 +8227 +16660 +6741 -162551 -168319 -16128 +178919 0 -300125 -371016 +104179 -14439 188.834 69.950 232.991 238.932 5.740 197.653 213.795 186.251 200.958 219.330 229.597 267.066 269.917 306.647 348.945 269.562 387.979 427.805 466.514 360.575 239.709 282.444 192.572 525.90 32.056 248.212 256.769 219.957 171.80 本表引自：C Borgnakke ，R E Sonntag. Thermodynamic and Transport Properties. New York ：John Wiley & Sons Inc ，1997 37